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Bridged Cyclopentane Synthesis via Catalytic Decarbonylative Cycloaddition between Cyclobutanones and Olefins
Herein we report an intramolecular rhodium-catalyzed decarbonylative coupling between cyclobutanones and alkenes via C–C activation, which provides a distinct approach to access a diverse range of saturated bridged cyclopentanes. In this reaction, cyclobutanones serve as a cyclopropane surrogate, of...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5214575/ https://ncbi.nlm.nih.gov/pubmed/27712025 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201608158 |
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