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Cooperative activation of cyclobutanones and olefins leads to bridged-ring systems by a catalytic [4+2] coupling

Bridged-ring systems are widely found in natural products and successful syntheses of them frequently feature intramolecular Diels-Alder (IMDA) reactions. These reactions are subclassified as either type I or type II IMDAs depending on how the diene motif is tethered to the rest of the substrate - t...

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Hlavní autoři: Ko, Haye Min, Dong, Guangbin
Médium: Artigo
Jazyk:Inglês
Vydáno: 2014
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC4150356/
https://ncbi.nlm.nih.gov/pubmed/25054946
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.1989
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