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Fused-Ring Formation by an Intramolecular “Cut-and-Sew” Reaction between Cyclobutanones and Alkynes

The development of a catalytic intramolecular “cut-and-sew” transformation between cyclobutanones and alkynes to construct cyclohexenone-fused rings is described herein. The challenge arises from the need for selective coupling at the more sterically hindered proximal position, and can be addressed...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Deng, Lin, Jin, Likun, Dong, Guangbin
Formato: Artigo
Idioma:Inglês
Publicado em: 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5849476/
https://ncbi.nlm.nih.gov/pubmed/29338109
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201712487
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