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Catalytic intramolecular decarbonylative coupling of 3-aminocyclobutenones and alkenes: a unique approach to [3.1.0] bicycles

Here we describe a rhodium-catalyzed intramolecular decarbonylative coupling between 3-aminocyclobutenones and alkenes for synthesis of substituted [3.1.0] bicycles. This transformation represents a formal cyclopropanation reaction, in which the cyclobutenones serve as a one-carbon-unit synthon.

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Detaylı Bibliyografya
Yayımlandı:Tetrahedron
Asıl Yazarlar: Zhou, Xuan, Zafar, Imran, Dong, Guangbin
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2015
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC4448780/
https://ncbi.nlm.nih.gov/pubmed/26034330
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.02.087
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