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Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate
A mild aerobic intramolecular aminoacetoxylation method for the synthesis of pyrrolidine and indoline derivatives was achieved using molecular oxygen as oxidant. A catalytic NO(x) species acts as an electron transfer mediator to access a high-valent palladium intermediate as the presumed active oxid...
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| Pubblicato in: | Org Lett |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5512709/ https://ncbi.nlm.nih.gov/pubmed/27754689 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02722 |
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