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Aerobic, Palladium-Catalyzed Dioxygenation of Alkenes Enabled by Catalytic Nitrite
Catalytic nitrite was found to enable carbon-oxygen bond-forming reductive elimination from unstable alkyl palladium intermediates, providing dioxygenated products from alkenes. A variety of functional groups are tolerated and high yields (up to 94%) are observed with many substrates, including a mu...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4285779/ https://ncbi.nlm.nih.gov/pubmed/25376666 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201408650 |
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