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Aerobic Metal-Free Dioxygenation of Alkenes with tert-Butyl Nitrite and N-Hydroxylamines

[Image: see text] Metal-free dioxygenation of alkenes with tert-butyl nitrite and N-hydroxylamines (N-hydroxyphthalimide, N-hydroxybenzotriazole, and N-hydroxysuccinimide) is described to produce β-aminoxy nitrate esters using air as the oxidant. These organic nitrates can be readily converted into...

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發表在:ACS Omega
Main Authors: Bag, Raghunath, Sar, Dinabandhu, Punniyamurthy, Tharmalingam
格式: Artigo
語言:Inglês
出版: American Chemical Society 2017
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC6644589/
https://ncbi.nlm.nih.gov/pubmed/31457873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.7b01111
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