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Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate
A mild aerobic intramolecular aminoacetoxylation method for the synthesis of pyrrolidine and indoline derivatives was achieved using molecular oxygen as oxidant. A catalytic NO(x) species acts as an electron transfer mediator to access a high-valent palladium intermediate as the presumed active oxid...
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| 出版年: | Org Lett |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5512709/ https://ncbi.nlm.nih.gov/pubmed/27754689 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b02722 |
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