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Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride
The development of the first enantio-, diastereo-, and regioselective iridium-catalyzed allylic alkylation reaction of prochiral enolates to form an all-carbon quaternary stereogenic center with an aliphatic-substituted allylic electrophile is disclosed. The reaction proceeds with good to excellent...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5207348/ https://ncbi.nlm.nih.gov/pubmed/27891825 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201609960 |
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