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Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation

[Image: see text] Feedstocks to Building Blocks. Transfer hydrogenative coupling of styrene with primary alcohols delivers branched or linear adducts from benzylic or aliphatic alcohols when modified by AgOTf or HBF(4), respectively. Related 2-propanol mediated reductive couplings also are described...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Xiao, Hongde, Wang, Gang, Krische, Michael J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5189692/
https://ncbi.nlm.nih.gov/pubmed/27910228
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201609056
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