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Direct Vinylation of Alcohols or Aldehydes Employing Alkynes as Vinyl Donors: A Ruthenium Catalyzed C-C Bond Forming Transfer Hydrogenation

[Image: see text] Under the conditions of ruthenium catalyzed transfer hydrogenation, 2-butyne couples to benzylic and aliphatic alcohols 1a–1i to furnish allylic alcohols 2a–2i, constituting a direct C-H vinylation of alcohols employing alkynes as vinyl donors. Under related transfer hydrogenation...

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Detalhes bibliográficos
Main Authors: Patman, Ryan L., Chaulagain, Mani Raj, Williams, Vanessa M., Krische, Michael J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3165010/
https://ncbi.nlm.nih.gov/pubmed/19173651
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja809456u
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