Colossal kinetic isotope effects in proton-coupled electron transfer

The kinetics of reduction of benzoquinone (Q) to hydroquinone (H(2)Q) by the Os(IV) hydrazido (trans-[Os(IV)(tpy)(Cl)(2)(N(H)N(CH(2))(4)O)]-PF(6) = [1]PF(6), tpy = 2,2′:6′,2″-terpyridine), sulfilimido (trans-[Os(IV)-(tpy)(Cl)(2)(NS(H)-4-C(6)H(4)Me)]PF(6) = [2]PF(6)), and phosphoraniminato (trans-[Os...

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Wedi'i Gadw mewn:
Manylion Llyfryddiaeth
Cyhoeddwyd yn:Proc Natl Acad Sci U S A
Prif Awduron: Huynh, My Hang V., Meyer, Thomas J.
Fformat: Artigo
Iaith:Inglês
Cyhoeddwyd: National Academy of Sciences 2004
Pynciau:
Physical Sciences
Mynediad Ar-lein:https://ncbi.nlm.nih.govhttps://pmc.ncbi.nlm.nih.gov/articles/PMC516537/
https://ncbi.nlm.nih.govhttps://pubmed.ncbi.nlm.nih.gov/15331783/
https://ncbi.nlm.nih.govhttps://doi.org/10.1073/pnas.0405086101
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