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Proton-Coupled Electron Transfer Reactions: Analytical Rate Constants and Case Study of Kinetic Isotope Effects in Lipoxygenase

A general theory has been developed for proton-coupled electron transfer (PCET), which is vital to a wide range of chemical and biological processes. This theory describes PCET reactions in terms of nonadiabatic transitions between reactant and product electron-proton vibronic states and includes th...

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Dettagli Bibliografici
Pubblicato in:Faraday Discuss
Autori principali: Soudackov, Alexander V., Hammes-Schiffer, Sharon
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
Soggetti:
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5217758/
https://ncbi.nlm.nih.gov/pubmed/27735009
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6fd00122j
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