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Kinetics teach that electronic coupling lowers the free-energy change that accompanies electron transfer
Electron-transfer theories predict that an increase in the quantum-mechanical mixing (H(DA)) of electron donor and acceptor wavefunctions at the instant of electron transfer drives equilibrium constants toward unity. Kinetic and equilibrium studies of four acceptor–bridge–donor (A-B-D) compounds rep...
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6048547/ https://ncbi.nlm.nih.gov/pubmed/29941573 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1722401115 |
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