Kinetics teach that electronic coupling lowers the free-energy change that accompanies electron transfer

Electron-transfer theories predict that an increase in the quantum-mechanical mixing (H(DA)) of electron donor and acceptor wavefunctions at the instant of electron transfer drives equilibrium constants toward unity. Kinetic and equilibrium studies of four acceptor–bridge–donor (A-B-D) compounds rep...

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Udgivet i:Proc Natl Acad Sci U S A
Main Authors: Sampaio, Renato N., Piechota, Eric J., Troian-Gautier, Ludovic, Maurer, Andrew B., Hu, Ke, Schauer, Phil A., Blair, Amber D., Berlinguette, Curtis P., Meyer, Gerald J.
Format: Artigo
Sprog:Inglês
Udgivet: National Academy of Sciences 2018
Fag:
Physical Sciences
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6048547/
https://ncbi.nlm.nih.gov/pubmed/29941573
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1722401115
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