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Colossal kinetic isotope effects in proton-coupled electron transfer
The kinetics of reduction of benzoquinone (Q) to hydroquinone (H(2)Q) by the Os(IV) hydrazido (trans-[Os(IV)(tpy)(Cl)(2)(N(H)N(CH(2))(4)O)]-PF(6) = [1]PF(6), tpy = 2,2′:6′,2″-terpyridine), sulfilimido (trans-[Os(IV)-(tpy)(Cl)(2)(NS(H)-4-C(6)H(4)Me)]PF(6) = [2]PF(6)), and phosphoraniminato (trans-[Os...
Tallennettuna:
| Päätekijät: | , |
|---|---|
| Aineistotyyppi: | Artigo |
| Kieli: | Inglês |
| Julkaistu: |
National Academy of Sciences
2004
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| Aiheet: | |
| Linkit: | https://ncbi.nlm.nih.gov/pmc/articles/PMC516537/ https://ncbi.nlm.nih.gov/pubmed/15331783 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0405086101 |
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