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Enantioselective Palladium-Catalyzed Alkenylation of Trisubstituted Alkenols to form Allylic Quaternary Centers
In this report, we describe the generation of remote allylic quaternary stereocenters β, γ, and δ relative to a carbonyl in high enantioselectivity. We utilize a redox-relay Heck reaction between alkenyl triflates and acyclic trisubstituted alkenols of varying chain-lengths. A wide array of terminal...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2016
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5152571/ https://ncbi.nlm.nih.gov/pubmed/27768842 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09649 |
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