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Reactions of HDDA-derived Benzynes with Sulfides: Mechanism, Modes, and Three-component Reactions
We report here reactions of alkyl sulfides with benzynes thermally generated by the hexadehydro-Diels–Alder (HDDA) cycloisomerization. The initially produced 1,3-betaine (o-sulfonium/aryl carbanion) undergoes intramolecular proton transfer to generate a more stable S-aryl sulfur ylide. This can reac...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5136460/ https://ncbi.nlm.nih.gov/pubmed/27010747 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01025 |
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