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An Atypical Mode of [3+2]-Cycloaddition: Pseudo-1,3-Dipole Behavior in Reactions of Electron-Deficient Thioamides with Benzynes

Thioamides bearing electron-withdrawing groups on the thiocarbonyl carbon atom react with benzynes [generated by the hexadehydro-Diels–Alder (HDDA) cycloisomerization] in an unprecedented fashion. Namely, the dihydrobenzothiazole products are consistent with a pathway involving initial formation of...

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Bibliografiske detaljer
Udgivet i:Org Lett
Main Authors: Zhang, Juntian, Page, Annika C. S., Palani, Vignesh, Chen, Junhua, Hoye, Thomas R.
Format: Artigo
Sprog:Inglês
Udgivet: 2018
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC6311210/
https://ncbi.nlm.nih.gov/pubmed/30156418
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.8b02133
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