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Reactions of HDDA-derived Benzynes with Sulfides: Mechanism, Modes, and Three-component Reactions

We report here reactions of alkyl sulfides with benzynes thermally generated by the hexadehydro-Diels–Alder (HDDA) cycloisomerization. The initially produced 1,3-betaine (o-sulfonium/aryl carbanion) undergoes intramolecular proton transfer to generate a more stable S-aryl sulfur ylide. This can reac...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Chen, Junhua, Palani, Vignesh, Hoye, Thomas R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5136460/
https://ncbi.nlm.nih.gov/pubmed/27010747
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b01025
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