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NMR Crystallography of a Carbanionic Intermediate in Tryptophan Synthase: Chemical Structure, Tautomerization, and Reaction Specificity
[Image: see text] Carbanionic intermediates play a central role in the catalytic transformations of amino acids performed by pyridoxal-5′-phosphate (PLP)-dependent enzymes. Here, we make use of NMR crystallography—the synergistic combination of solid-state nuclear magnetic resonance, X-ray crystallo...
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| Izdano u: | J Am Chem Soc |
|---|---|
| Glavni autori: | , , , , , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American Chemical
Society
2016
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| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5129030/ https://ncbi.nlm.nih.gov/pubmed/27779384 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b08937 |
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