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Protonation States of the Tryptophan Synthase Internal Aldimine Active Site from Solid-State NMR Spectroscopy: Direct Observation of the Protonated Schiff Base Linkage to Pyridoxal-5′-Phosphate
[Image: see text] The acid–base chemistry that drives catalysis in pyridoxal-5′-phosphate (PLP)-dependent enzymes has been the subject of intense interest and investigation since the initial identification of PLP’s role as a coenzyme in this extensive class of enzymes. It was first proposed over 50...
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| Asıl Yazarlar: | , , , , , , , , , , , |
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| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
American Chemical
Society
2014
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| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4183654/ https://ncbi.nlm.nih.gov/pubmed/25148001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506267d |
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