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Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes
Aromatic cation activation is a useful strategy to promote deoxyfunctionalization; however, the deoxyfluorination of alcohols with cyclopropenium cation remains an unsolved problem due to the weak nucleophilicity of fluoride ion. Here we report the use of 3,3-difluoro-1,2-diarylcyclopropenes (CpFluo...
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| Publicado no: | Nat Commun |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Nature Publishing Group
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5114535/ https://ncbi.nlm.nih.gov/pubmed/27841256 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/ncomms13320 |
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