Stereo‐ and Regioselective Alkyne Hydrometallation with Gold(III) Hydrides

The hydroauration of internal and terminal alkynes by gold(III) hydride complexes [(C^N^C)AuH] was found to be mediated by radicals and proceeds by an unexpected binuclear outer‐sphere mechanism to cleanly form trans‐insertion products. Radical precursors such as azobisisobutyronitrile lead to a dra...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Pintus, Anna, Rocchigiani, Luca, Fernandez‐Cestau, Julio, Budzelaar, Peter H. M., Bochmann, Manfred
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2016
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5113781/
https://ncbi.nlm.nih.gov/pubmed/27592697
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201607522
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