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Total Synthesis, Structure, and Biological Activity of Adenosylrhodibalamin, the Non‐Natural Rhodium Homologue of Coenzyme B(12)
B(12) is unique among the vitamins as it is biosynthesized only by certain prokaryotes. The complexity of its synthesis relates to its distinctive cobalt corrin structure, which is essential for B(12) biochemistry and renders coenzyme B(12) (AdoCbl) so intriguingly suitable for enzymatic radical rea...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
John Wiley and Sons Inc.
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5103170/ https://ncbi.nlm.nih.gov/pubmed/27355790 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603738 |
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