Total Synthesis, Structure, and Biological Activity of Adenosylrhodibalamin, the Non‐Natural Rhodium Homologue of Coenzyme B(12)

B(12) is unique among the vitamins as it is biosynthesized only by certain prokaryotes. The complexity of its synthesis relates to its distinctive cobalt corrin structure, which is essential for B(12) biochemistry and renders coenzyme B(12) (AdoCbl) so intriguingly suitable for enzymatic radical rea...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Widner, Florian J., Lawrence, Andrew D., Deery, Evelyne, Heldt, Dana, Frank, Stefanie, Gruber, Karl, Wurst, Klaus, Warren, Martin J., Kräutler, Bernhard
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5103170/
https://ncbi.nlm.nih.gov/pubmed/27355790
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603738
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