Zinc Substitution of Cobalt in Vitamin B(12): Zincobyric acid and Zincobalamin as Luminescent Structural B(12)‐Mimics

Replacing the central cobalt ion of vitamin B(12) by other metals has been a long‐held aspiration within the B(12)‐field. Herein, we describe the synthesis from hydrogenobyric acid of zincobyric acid (Znby) and zincobalamin (Znbl), the Zn‐analogues of the natural cobalt‐corrins cobyric acid and vita...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Kieninger, Christoph, Baker, Joseph A., Podewitz, Maren, Wurst, Klaus, Jockusch, Steffen, Lawrence, Andrew D., Deery, Evelyne, Gruber, Karl, Liedl, Klaus R., Warren, Martin J., Kräutler, Bernhard
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6790578/
https://ncbi.nlm.nih.gov/pubmed/31420932
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908428
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