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Stereospecific effects of oxygen-to-sulfur substitution in DNA phosphate on ion-pair dynamics and protein-DNA affinity

Oxygen-to-sulfur substitutions in DNA phosphate often enhance affinity for DNA-binding proteins. Our previous studies have suggested that this effect of sulfur substitution of both O(P1) and O(P2) atoms is due to an entropic gain associated with enhanced ion-pair dynamics. In this work, we studied s...

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Detalhes bibliográficos
Publicado no:Chembiochem
Main Authors: Nguyen, Dan, Zandarashvili, Levani, White, Mark A., Iwahara, Junji
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5096788/
https://ncbi.nlm.nih.gov/pubmed/27271797
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/cbic.201600265
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