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An enantioselective synthesis of the C3–C21 segment of the macrolide immunosuppressive agent FR252921

An enantioselective synthesis of the C3–C21 segment of the novel immunosuppressant FR252921 is described. The C12 and C13 stereogenic centers were constructed by a non-aldol process utilizing optically active 4-phenylbutyrolactone. The C18 stereogenic center was installed using Braun's highly d...

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Publicat a:Tetrahedron Lett
Autors principals: Ghosh, Arun K., Rodriguez, Samuel
Format: Artigo
Idioma:Inglês
Publicat: 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5094281/
https://ncbi.nlm.nih.gov/pubmed/27818534
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2016.05.067
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