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A chiral analog of the bicyclic guanidine TBD: synthesis, structure and Brønsted base catalysis
Starting from (S)-β-phenylalanine, easily accessible by lipase-catalyzed kinetic resolution, a chiral triamine was assembled by a reductive amination and finally cyclized to form the title compound 10. In the crystals of the guanidinium benzoate salt the six membered rings of 10 adopt conformations...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5082680/ https://ncbi.nlm.nih.gov/pubmed/27829893 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.176 |
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