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Harnessing C–H Borylation/Deborylation for Selective Deuteration, Synthesis of Boronate Esters, and Late Stage Functionalization

Ir-catalyzed deborylation can be used to selectively deuterate aromatic and heteroaromatic substrates. Combined with the selectivities of Ir-catalyzed C–H borylations, uniquely labeled compounds can be prepared. In addition, diborylation/deborylation reactions provide monoborylated regioisomers that...

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Publicat a:J Org Chem
Autors principals: Kallepalli, Venkata A, Gore, Kristin A., Shi, Feng, Sanchez, Luis, Chotana, Ghayoor A., Miller, Susanne L., Maleczka, Robert E., Smith, Milton R.
Format: Artigo
Idioma:Inglês
Publicat: 2015
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5080619/
https://ncbi.nlm.nih.gov/pubmed/26226056
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.5b01588
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