Á lódáil...
Outer-Sphere Direction in Iridium C-H Borylation
The NHBoc group affords ortho selective C–H borylations in arenes and alkenes. Experimental and computational studies support an outer sphere mechanism where the N–H proton hydrogen bonds to a boryl ligand oxygen. The regioselectivities are unique and complement those of directed ortho metalations....
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| Main Authors: | , , , , , |
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| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2012
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3587652/ https://ncbi.nlm.nih.gov/pubmed/22703452 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303443m |
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