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Outer-Sphere Direction in Iridium C-H Borylation

The NHBoc group affords ortho selective C–H borylations in arenes and alkenes. Experimental and computational studies support an outer sphere mechanism where the N–H proton hydrogen bonds to a boryl ligand oxygen. The regioselectivities are unique and complement those of directed ortho metalations....

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Autors principals: Roosen, Philipp C., Kallepalli, Venkata A., Chattopadhyay, Buddhadeb, Singleton, Daniel A., Maleczka, Robert E., Smith, Milton R.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3587652/
https://ncbi.nlm.nih.gov/pubmed/22703452
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303443m
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