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Boc Groups as Protectors and Directors for Ir-Catalyzed C–H Borylation of Heterocycles
[Image: see text] Ir-catalyzed C–H borylation is found to be compatible with Boc protecting groups. Thus, pyrroles, indoles, and azaindoles can be selectively functionalized at C–H positions β to N. The Boc group can be removed on thermolysis or left intact during subsequent transformations.
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| Main Authors: | , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3876461/ https://ncbi.nlm.nih.gov/pubmed/19894699 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo901822b |
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