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Mechanism of H(2) Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides
The intermediacy of a reduced nickel–iron hydride in hydrogen evolution catalyzed by Ni–Fe complexes was verified experimentally and computationally. In addition to catalyzing hydrogen evolution, the highly basic and bulky (dppv)Ni(μ-pdt)Fe(CO)(dppv) ([1](0); dppv = cis-C(2)H(2)(PPh(2))(2)) and its...
Gorde:
| Argitaratua izan da: | J Am Chem Soc |
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| Egile Nagusiak: | , , , , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
2016
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5029088/ https://ncbi.nlm.nih.gov/pubmed/27328053 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04579 |
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