Mechanism of H(2) Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides

The intermediacy of a reduced nickel–iron hydride in hydrogen evolution catalyzed by Ni–Fe complexes was verified experimentally and computationally. In addition to catalyzing hydrogen evolution, the highly basic and bulky (dppv)Ni(μ-pdt)Fe(CO)(dppv) ([1](0); dppv = cis-C(2)H(2)(PPh(2))(2)) and its...

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Pubblicato in:J Am Chem Soc
Autori principali: Ulloa, Olbelina A., Huynh, Mioy T., Richers, Casseday P., Bertke, Jeffery A., Nilges, Mark J., Hammes-Schiffer, Sharon, Rauchfuss, Thomas B.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2016
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5029088/
https://ncbi.nlm.nih.gov/pubmed/27328053
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04579
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