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Anatomy of the β-branching enzyme of polyketide biosynthesis and its interaction with an acyl-ACP substrate
Alkyl branching at the β position of a polyketide intermediate is an important variation on canonical polyketide natural product biosynthesis. The branching enzyme, 3-hydroxy-3-methylglutaryl synthase (HMGS), catalyzes the aldol addition of an acyl donor to a β-keto-polyketide intermediate acceptor....
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| Publicado no: | Proc Natl Acad Sci U S A |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
National Academy of Sciences
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5027445/ https://ncbi.nlm.nih.gov/pubmed/27573844 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1607210113 |
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