Synthesis and Reactivity of Four- and Five-Coordinate Low-Spin Cobalt(II) PCP Pincer Complexes and Some Nickel(II) Analogues

[Image: see text] Anhydrous CoCl(2) or [NiCl(2)(DME)] reacts with the ligand PCP(Me)-iPr (1) in the presence of nBuLi to afford the 15e and 16e square planar complexes [Co(PCP(Me)-iPr)Cl] (2) and [Ni(PCP(Me)-iPr)Cl] (3), respectively. Complex 2 is a paramagnetic d(7) low-spin complex, which is a use...

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Detalhes bibliográficos
Publicado no:Organometallics
Main Authors: Murugesan, Sathiyamoorthy, Stöger, Berthold, Carvalho, Maria Deus, Ferreira, Liliana P., Pittenauer, Ernst, Allmaier, Günter, Veiros, Luis F., Kirchner, Karl
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2014
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5021385/
https://ncbi.nlm.nih.gov/pubmed/27642210
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om5007769
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