Synthesis, Structure, and Reactivity of Co(II) and Ni(II) PCP Pincer Borohydride Complexes

[Image: see text] The 15e square-planar complexes [Co(PCP(Me)-iPr)Cl] (2a) and [Co(PCP-tBu)Cl] (2b), respectively, react readily with NaBH(4) to afford complexes [Co(PCP(Me)-iPr)(η(2)-BH(4))] (4a) and [Co(PCP-tBu)(η(2)-BH(4))] (4b) in high yields, as confirmed by IR spectroscopy, X-ray crystallograp...

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Bibliografske podrobnosti
izdano v:Organometallics
Main Authors: Murugesan, Sathiyamoorthy, Stöger, Berthold, Weil, Matthias, Veiros, Luis F., Kirchner, Karl
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2015
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5021384/
https://ncbi.nlm.nih.gov/pubmed/27642212
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.organomet.5b00075
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