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Palladium‐Catalyzed Oxidative Synthesis of α‐Acetoxylated Enones from Alkynes
We report a palladium‐catalyzed oxidative functionalization of alkynes to generate α‐acetoxylated enones in one step. A range of functional groups are well‐tolerated in this reaction. Mechanistic studies, including the use of (18)O‐labeled DMSO, revealed that the ketone oxygen atom in the product or...
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| Yayımlandı: | Angew Chem Int Ed Engl |
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| Asıl Yazarlar: | , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
John Wiley and Sons Inc.
2016
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5021131/ https://ncbi.nlm.nih.gov/pubmed/27060476 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600696 |
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