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Palladium‐Catalyzed Oxidative Synthesis of α‐Acetoxylated Enones from Alkynes

We report a palladium‐catalyzed oxidative functionalization of alkynes to generate α‐acetoxylated enones in one step. A range of functional groups are well‐tolerated in this reaction. Mechanistic studies, including the use of (18)O‐labeled DMSO, revealed that the ketone oxygen atom in the product or...

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Détails bibliographiques
Publié dans:Angew Chem Int Ed Engl
Auteurs principaux: Jiang, Tuo, Quan, Xu, Zhu, Can, Andersson, Pher G., Bäckvall, Jan‐E.
Format: Artigo
Langue:Inglês
Publié: John Wiley and Sons Inc. 2016
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5021131/
https://ncbi.nlm.nih.gov/pubmed/27060476
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201600696
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