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Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C–H Activation/Carbocyclization of Arylallenes
[Image: see text] Herein we report an example of tandem oxidative acetoxylation/carbocyclization of arylallenes 1 using Pd(OAc)(2). The catalytic protocol is highly selective and provides access to new C–C and C–O bonds leading to a carbocyclization. The reaction proceeds via C–H activation by Pd. M...
Shranjeno v:
| izdano v: | J Am Chem Soc |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
American Chemical
Society
2015
|
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4557776/ https://ncbi.nlm.nih.gov/pubmed/26201012 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06068 |
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