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Palladium(II)-Catalyzed Tandem Oxidative Acetoxylation/ortho C–H Activation/Carbocyclization of Arylallenes

[Image: see text] Herein we report an example of tandem oxidative acetoxylation/carbocyclization of arylallenes 1 using Pd(OAc)(2). The catalytic protocol is highly selective and provides access to new C–C and C–O bonds leading to a carbocyclization. The reaction proceeds via C–H activation by Pd. M...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Mazuela, Javier, Banerjee, Debasis, Bäckvall, Jan-E.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2015
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4557776/
https://ncbi.nlm.nih.gov/pubmed/26201012
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b06068
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