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Palladium‐Catalyzed Oxidative Carbocyclization–Borylation of Enallenes to Cyclobutenes

A highly efficient palladium‐catalyzed oxidative borylation of enallenes was developed for the selective formation of cyclobutene derivatives and fully‐substituted alkenylboron compounds. Cyclobutenes are formed as the exclusive products in MeOH in the presence of H(2)O and Et(3)N, whereas the use o...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Qiu, Youai, Yang, Bin, Zhu, Can, Bäckvall, Jan‐E.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5021125/
https://ncbi.nlm.nih.gov/pubmed/27088425
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601613
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