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Palladium‐Catalyzed Oxidative Carbocyclization–Borylation of Enallenes to Cyclobutenes

A highly efficient palladium‐catalyzed oxidative borylation of enallenes was developed for the selective formation of cyclobutene derivatives and fully‐substituted alkenylboron compounds. Cyclobutenes are formed as the exclusive products in MeOH in the presence of H(2)O and Et(3)N, whereas the use o...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Qiu, Youai, Yang, Bin, Zhu, Can, Bäckvall, Jan‐E.
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2016
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5021125/
https://ncbi.nlm.nih.gov/pubmed/27088425
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601613
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