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Trifluoromethylation of Arylsilanes with (phen)CuCF(3)
A method for the trifluoromethylation of arylsilanes is reported. The reaction occurs with (phen)CuCF(3) as the CF(3)-source under mild, oxidative conditions with high functional group compatibility. This transformation complements prior trifluoromethylation of arenes in several ways. Most important...
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| Udgivet i: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2016
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4976628/ https://ncbi.nlm.nih.gov/pubmed/27214849 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601163 |
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