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Trifluoromethylation of Arylsilanes with (phen)CuCF(3)

A method for the trifluoromethylation of arylsilanes is reported. The reaction occurs with (phen)CuCF(3) as the CF(3)-source under mild, oxidative conditions with high functional group compatibility. This transformation complements prior trifluoromethylation of arenes in several ways. Most important...

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發表在:Angew Chem Int Ed Engl
Main Authors: Morstein, Johannes, Hou, Haiyun, Cheng, Chen, Hartwig, John F.
格式: Artigo
語言:Inglês
出版: 2016
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4976628/
https://ncbi.nlm.nih.gov/pubmed/27214849
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201601163
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