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C-Propargylation Overrides O-Propargylation in Reactions of Propargyl Chloride with Primary Alcohols via Rhodium Catalyzed Transfer Hydrogenation
A Path Less Travelled. The canonical S(N)2 behavior displayed by alcohols and activated alkyl halides in basic media (O-alkylation) is superseded by a pathway leading to carbinol C-alkylation under the conditions of rhodium catalyzed transfer hydrogenation. Racemic and asymmetric propargylations are...
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| 出版年: | Angew Chem Int Ed Engl |
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| 主要な著者: | , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2016
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4965293/ https://ncbi.nlm.nih.gov/pubmed/27321353 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603575 |
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