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C-Propargylation Overrides O-Propargylation in Reactions of Propargyl Chloride with Primary Alcohols via Rhodium Catalyzed Transfer Hydrogenation
A Path Less Travelled. The canonical S(N)2 behavior displayed by alcohols and activated alkyl halides in basic media (O-alkylation) is superseded by a pathway leading to carbinol C-alkylation under the conditions of rhodium catalyzed transfer hydrogenation. Racemic and asymmetric propargylations are...
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| Publié dans: | Angew Chem Int Ed Engl |
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| Auteurs principaux: | , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2016
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4965293/ https://ncbi.nlm.nih.gov/pubmed/27321353 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201603575 |
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