Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates

Fe(III)–hypohalite complexes have been implicated in a wide range of important enzyme‐catalyzed halogenation reactions including the biosynthesis of natural products and antibiotics and post‐translational modification of proteins. The absence of spectroscopic data on such species precludes their ide...

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Détails bibliographiques
Publié dans:Angew Chem Weinheim Bergstr Ger
Auteurs principaux: Draksharapu, Apparao, Angelone, Davide, Quesne, Matthew G., Padamati, Sandeep K., Gómez, Laura, Hage, Ronald, Costas, Miquel, Browne, Wesley R., de Visser, Sam P.
Format: Artigo
Langue:Inglês
Publié: WILEY‐VCH Verlag 2015
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4955228/
https://ncbi.nlm.nih.gov/pubmed/27478260
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ange.201411995
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