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Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates

Fe(III)–hypohalite complexes have been implicated in a wide range of important enzyme‐catalyzed halogenation reactions including the biosynthesis of natural products and antibiotics and post‐translational modification of proteins. The absence of spectroscopic data on such species precludes their ide...

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Detalhes bibliográficos
Publicado no:Angew Chem Weinheim Bergstr Ger
Main Authors: Draksharapu, Apparao, Angelone, Davide, Quesne, Matthew G., Padamati, Sandeep K., Gómez, Laura, Hage, Ronald, Costas, Miquel, Browne, Wesley R., de Visser, Sam P.
Formato: Artigo
Idioma:Inglês
Publicado em: WILEY‐VCH Verlag 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4955228/
https://ncbi.nlm.nih.gov/pubmed/27478260
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/ange.201411995
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