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Towards the total synthesis of keramaphidin B
The enantio- and diastereoselective Michael addition of a δ-valerolactone-derived pronucleophile to a substituted furanyl nitroolefin catalysed by a bifunctional cinchonine-derived thiourea has been used as the key stereocontrolling step in a new synthetic strategy to the heavily functionalised pipe...
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| Published in: | Beilstein J Org Chem |
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| Main Authors: | , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
Beilstein-Institut
2016
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4901993/ https://ncbi.nlm.nih.gov/pubmed/27340496 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.12.104 |
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