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Enantioselective synthesis of (–)-chloramphenicol via silver-catalysed asymmetric isocyanoacetate aldol reaction
The highly enantio- and diastereoselective aldol reaction of isocyanoacetates catalysed by Ag(2)O and cinchona-derived amino phosphines applied to the synthesis of (–)- and (+)-chloramphenicol is described. The concise synthesis showcases the utility of this catalytic asymmetric methodology for the...
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| Publicado no: | Org Biomol Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4756631/ https://ncbi.nlm.nih.gov/pubmed/26510469 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5ob02141c |
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