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Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates**
A catalytic asymmetric aldol addition/cyclization reaction of unactivated ketones with isocyanoacetate pronucleophiles has been developed. A quinine-derived aminophosphine precatalyst and silver oxide were found to be an effective binary catalyst system and promoted the reaction to afford chiral oxa...
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| Foilsithe in: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
WILEY-VCH Verlag
2015
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4678506/ https://ncbi.nlm.nih.gov/pubmed/25735645 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201411852 |
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