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Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates**

A catalytic asymmetric aldol addition/cyclization reaction of unactivated ketones with isocyanoacetate pronucleophiles has been developed. A quinine-derived aminophosphine precatalyst and silver oxide were found to be an effective binary catalyst system and promoted the reaction to afford chiral oxa...

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Bibliografische gegevens
Gepubliceerd in:Angew Chem Int Ed Engl
Hoofdauteurs: delaCampa, Raquel, Ortín, Irene, Dixon, Darren J
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: WILEY-VCH Verlag 2015
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4678506/
https://ncbi.nlm.nih.gov/pubmed/25735645
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201411852
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